Potassium dichromate, CAS# 7778-50-9
Mary Tang
mtang at stanford.edu
Wed Oct 7 12:30:58 PDT 2009
Hi Khanh --
As discussed, this should be fine. However, please collect waste
locally and label appropriately instead of using the HF drain.
Thanks,
Mary
Khanh Hoang wrote:
>
>
>
> Hello Mahnaz and Marry,
>
>
>
> I would like to bring a new chemical into the SNF lab. Here is the
> information:
>
>
>
> (1) Contact Information:
>
> · Name: Khanh Hoang
>
> · Coral login: khoang
>
> NanoGram Corp.
>
> 165 Topaz Street
>
> Milpitas, CA 95035
>
> Tel: (408) 719-5356
>
> Fax: (408) 262-6290
>
> Cell phone: (408) 786-6441
>
>
>
> (2) The chemical: Potassium dichromate;
>
> * Synonyms: Potassium bichromate
>
> * CAS#: 7778-50-9
>
> * Storage group: *E* - Compatible Oxidizers, Organic Peroxides,
> and Acids.
>
> * Main hazard class: Oxidizers
>
>
>
> (3) Vendor/ Manufacturer info:
>
> · Vendor: Sigma-Aldrich,
> http://www.sigmaaldrich.com/catalog/ProductDetail.do?lang=en&N4=483044|ALDRICH&N5=SEARCH_CONCAT_PNO|BRAND_KEY&F=SPEC
> <http://www.sigmaaldrich.com/catalog/ProductDetail.do?lang=en&N4=483044%7CALDRICH&N5=SEARCH_CONCAT_PNO%7CBRAND_KEY&F=SPEC>
>
> · Phone: 800-325-3010
>
> (4) Reason for request:
>
> · We will perform Secco etching on polycrystalline Si wafers
> to etch defects.
>
> · Secco etch recipe: Mixture of *HF (48%)* + *K_2 Cr_2 O_7 *
> (*44 g K_2 Cr_2 O_7 * dissolved in *1 l* of the of *H_2 O, or 0.15 M)
> in a ratio of 2:1*
>
>
>
> (5) Process flow:
>
> * We will first dissolve Potassium dichromate with deionized water
> in a HDPE (high density polyethylene) plastic bottle at the
> chemicals handling bench (outside of the cleanroom).
> * The solution will then be transferred by a staff member to the
> Pass-through Carts.
> * We will mix the solution with HF (48%) and perform the etching
> process at the wbgen-hpr and use the Gold-contaminated labwares.
> * After the etching process we will process the samples outside of
> the cleanroom. However the purity level of the purchased
> potassium dichromate is greater than 99.99% trace metals basis.
>
>
>
> (6) Amount and form:
>
> · Amount: 44 grams
>
> · Form: solid
>
> · I will dissolve 44 grams in 1L of deionized water.
>
>
>
> (7) Storage: the potassium dichromate solution will be stored on
> top of one of the Pass-through Carts or in the bulk storage area.
>
>
>
> (8) Disposal: the spent mixture of potassium dichromate solution
> and HF will be disposed in the HF drain. Excess or unused potassium
> dichromate solution will be collected locally according to the SNF
> regulation (disposed in a clean, empty waste container, attached to
> the bottle with a filled hazardous waste disposal label, and place the
> container on the hazardous waste shelf in the chemcial pass-through).
>
>
>
> Please let me know if I can perform this task at SNF.
>
>
>
> Thanks so much for your help,
>
>
>
> Khanh Hoang
>
>
>
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