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Hydrofluoric Dip

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MSDS Number: H3996 * * * * * Effective Date: 06/13/07 * * * * * Supercedes: 05/07/07


HF DIP


1. Product Identification

Synonyms: None
CAS No.: 7664-39-3
Molecular Weight: 20.01
Chemical Formula: HF in Aqueous Solution.
Product Codes: 5291, 5331, 5339, 5351, 5391, 5397, 5421, 5450, 5477, 5545, 5829, 5871, 9283, 9286, 9288, 9561

2. Composition/Information on Ingredients

 

  Ingredient                                CAS No         Percent        Hazardous                                  
  ---------------------------------------   ------------   ------------   ---------   
 
  Hydrogen Fluoride                         7664-39-3          < 10%         Yes                                                                  
  Water                                     7732-18-5          > 90%         No                                                                   
 

3. Hazards Identification

Emergency Overview
--------------------------
POISON! DANGER! CORROSIVE. EXTREMELY HAZARDOUS LIQUID AND VAPOR. CAUSES SEVERE BURNS WHICH MAY NOT BE IMMEDIATELY PAINFUL OR VISIBLE. MAY BE FATAL IF SWALLOWED OR INHALED. LIQUID AND VAPOR CAN BURN SKIN, EYES AND RESPIRATORY TRACT. CAUSES BONE DAMAGE. REACTION WITH CERTAIN METALS GENERATES FLAMMABLE AND POTENTIALLY EXPLOSIVE HYDROGEN GAS.

SAF-T-DATA(tm) Ratings (Provided here for your convenience)
-----------------------------------------------------------------------------------------------------------
Health Rating: 4 - Extreme (Poison)
Flammability Rating: 0 - None
Reactivity Rating: 2 - Moderate
Contact Rating: 4 - Extreme (Corrosive)
Lab Protective Equip: GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES
Storage Color Code: White (Corrosive)
-----------------------------------------------------------------------------------------------------------

Potential Health Effects
----------------------------------

Exposure to hydrofluoric acid can produce harmful health effects that may not be immediately apparent.

Inhalation:
Severely corrosive to the respiratory tract. May cause sore throat, coughing, labored breathing and lung congestion/inflammation.
Ingestion:
Corrosive. May cause sore throat, abdominal pain, diarrhea, vomiting, severe burns of the digestive tract, and kidney dysfunction.
Skin Contact:
Corrosive to the skin. Skin contact causes serious skin burns which may not be immediately apparent or painful. Symptoms may be delayed 8 hours or longer. The fluoride ion readily penetrates the skin causing destruction of deep tissue layers and even bone.
Eye Contact:
Corrosive to the eyes. Symptoms of redness, pain, blurred vision, and permanent eye damage may occur.
Chronic Exposure:
Intake of more than 6 mg of fluorine per day may result in fluorosis, bone and joint damage. Hypocalcemia and hypomagnesemia can occur from absorption of fluoride ion into blood stream.
Aggravation of Pre-existing Conditions:
Persons with pre-existing skin disorders, eye problems, or impaired kidney or respiratory function may be more susceptible to the effects of this substance.

4. First Aid Measures

For any route of contact: Detailed First Aid procedure should be planned before beginning work with HF.
Inhalation:
Get medical help immediately. If patient is unconscious, give artificial respiration or use inhalator. Keep patient warm and resting, and send to hospital after first aid is complete.
Ingestion:
If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately.
Skin Contact:
1) Remove the victim from the contaminated area and immediately place him under a safety shower or wash him with a water hose, whichever is available. 2) Remove all contaminated clothing. Handle all HF-contaminated material with gloves made of appropriate material, such as PVC or neoprene. 3) Keep washing with large amounts of water for a minimum of 15 minutes. 4) Have someone make arrangements for medical attention while you continue flushing the affected area with water. 5) If the following materials are available, limit the washing to five minutes and immerse the burned area in a solution of 0.2% iced aqueous Hyamine 1622 or 0.13% iced aqueous Zephiran Chloride. If immersion is not practical, towels should be soaked with one of the above solutions and used as compresses for the burn area. Ideally compresses should be changed every 2 minutes. Alternately, 2.5% calcium gluconate gel should be massaged into the affected area. 6) Seek medical attention as soon as possible for all burns regardless of how minor they may appear initially. Hyamine 1622 is a trade name for tetracaine benzethonium chloride, Merck Index Monograph 1078, a quaternary ammonium compound sold by Rohm & Haas, Philadelphia. Zephiran Chloride is a trade name for benzalkonium chloride, Merck Index Monograph 1059, also a quaternary ammonium compound, sold by Sanofi-Synthelabo Inc., New York, NY.
Eye Contact:
1) Irrigate eyes for at least 30 minutes with copious quantities of water, keeping the eyelids apart and away from eyeballs during irrigation. 2) Get competent medical attention immediately, preferably an eye specialist. 3) If a physician is not immediately available, apply one or two drops of ophthalmic anesthetic, (e.g., 0.5% Pontocaine Hydrochloride solution). 4) Do not use oily drops, ointment or HF skin burn treatments. Place ice pack on eyes until reaching emergency room.

Note to Physician:
General: For burns of moderate areas, (greater than 8 square inches), ingestion and significant inhalation exposure, severe systemic effects may occur, and admission to a critical care unit should be considered. Monitor and correct for hypocalcemia, cardiac arrhythmias, hypomagnesemia and hyperkalemia. In some cases renal dialysis may be indicated.

Inhalation: Treat as chemical pneumonia. Monitor for hypocalcemia, 2.5% calcium gluconate in normal saline by nebulizer or by IPPB with 100% oxygen may decrease pulmonary damage. Bronchodilators may also be administered.

Skin: For deep skin burns or contact with concentrated HF (over 50%) solution, consider infiltration about the affected area with 5% calcium gluconate [equal parts of 10% calcium gluconate and sterile saline for injection]. Burns beneath the nail may require splitting the nail and application of calcium gluconate to the exposed nail bed. For certain burns, especially of the digits, use of intra-arterial calcium gluconate may be indicated.

Eyes: Irrigation may be facilitated by use of Morgan lens or similar ocular irrigator, using 1% aqueous calcium gluconate solution [50ml of calcium gluconate 10% in 500 ml normal saline].

AN ALTERNATIVE FIRST AID PROCEDURE: The effect of HF, i.e. onset of pain, particularly in dilute solutions, may not be felt for up to 24 hours. It is important, therefore, that persons using HF have immediate access to an effective antidote even when they are away from their work place in order that first aid treatment can be commenced immediately.
We recommend that any person in contact with HF should carry, or have access to a tube of HF Antidote Gel at all times; ideally with one tube at the work place, one on the person and one at home.
It is imperative that any person who has been contaminated by HF should seek medical advice when the treatment by HF Antidote Gel has been applied.
REFERENCES: 1. Browno, T.D. Treatment of Hydrofluoric Acid Burns 2. Sprout, W.L. et al Treatment of Severe Hydrofluoric Acid Exposures (Journal of American Occupational Medicine 25:12, 1993) 3. Bracken, W.M. et al Comparative Effectiveness of Topical Treatments for Hydrofluoric Acid Burns, University of Kansas (Journal of Occupational Medicine 27:10:1985) 4. Burke, W.J. , et al Systemic Fluoride Poisoning Resulting from A Fluoride Skin Burn (Journal of Occupational Medicine (5,39:1973)

HF ANTIDOTE GEL:
Distributed by Pharmascience Inc.
8400 Darnley Rd. Montreal, Canada. H4T 1M4
Phone: ( 514 ) 340 - 1114
Fax: ( 514 ) 342 - 7764
U.S. (Buffalo, NY) distributor: 1-800-207-4477


5. Fire Fighting Measures

Fire:
Not considered to be a fire hazard. Fire may produce poisonous or irritating gases.
Explosion:
Violent exothermic reaction occurs with water. Sufficient heat may be produced to ignite combustible materials. Reacts with metals forming flammable Hydrogen gas.
Fire Extinguishing Media:
Keep upwind of fire. Use water or carbon dioxide on fires in which Hydrofluoric Acid is involved. Halon or foam may also be used. In case of fire, the sealed containers can be kept cool by spraying with water.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. Avoid getting water in tanks or drums; water can cause generation of heat and spattering. In contact with air, the acid gives off corrosive fumes which are heavier than air.

6. Accidental Release Measures

Notify safety personnel, provide adequate ventilation, and remove ignition sources since hydrogen may be generated by reactions with metals. Wear appropriate personal protective equipment as specified in Section 8. Do not flush to sewers or waterways. Spills: Evacuate the danger area. Apply magnesium sulfate (dry) to the spill area. Follow up with inert absorbent and add soda ash or magnesium oxide and slaked lime. Collect in appropriate plastic containers and save for disposal. Wash spill site with soda ash solution. NOTE: Porous materials (concrete, wood, plastic, etc.) will absorb HF and become a hazard for an indefinite time. Such spills should be cleaned and neutralized immediately. US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-8802.


J. T. Baker NEUTRASORB� acid neutralizers are recommended for spills of this product.

7. Handling and Storage

Keep in tightly closed polyethylene containers. Store in a cool, dry place with adequate ventilation separated from other chemicals. Protect from physical damage. Storage facilities should be constructed for containment and neutralization of spills. Handling and storage of HF requires special materials and technology for containers, pipes, valves, etc., which is available from suppliers. Containers of this material may be hazardous when empty since they retain product residues (vapors, liquid); observe all warnings and precautions listed for the product.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits:
Hydrogen fluoride:
-OSHA Permissible Exposure Limit (PEL):
3 ppm (TWA)
ACGIH Threshold Limit Value (TLV):
3 ppm Ceiling as F
Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved):
If the exposure limit is exceeded, a full facepiece respirator with an acid gas cartridge may be worn up to 50 times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator. WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres. Since the IDLH is low (30 ppm), the above cartridge system is not specifically approved for HF. (3M Respirator Selection Guide)
Skin Protection:
Wear protective clothing, including boots or safety shoes with polyvinyl chloride (PVC) or neoprene. Use chemical goggles and/or a full face shield. Wear coveralls with long sleeves, gauntlets and gloves of PVC or neoprene. A high degree of protection is obtained with an air-inflated suit with mask and safety belt. Use protection suitable for conditions.
Eye Protection:
Use chemical safety goggles and/or full face shield where splashing is possible. Maintain eye wash fountain and quick drench facilities in work area.

9. Physical and Chemical Properties

Appearance:
Colorless liquid.
Odor:
Acrid odor. Do not breathe fumes.
Solubility:
Infinitely soluble.
Specific Gravity:
No information found.
pH:
1.0 (0.1M solution)
% Volatiles by volume @ 21C (70F):
No information found.
Boiling Point:
No information found.
Melting Point:
No information found.
Vapor Density (Air=1):
No information found.
Vapor Pressure (mm Hg):
No information found.
Evaporation Rate (BuAc=1):
No information found.

10. Stability and Reactivity

Stability:
Stable at room temperature (68F) when stored and used under proper conditions.
Hazardous Decomposition Products:
On contact with metals, liberates hydrogen gas. On heating to decomposition, could yield toxic fumes of fluorides. Attacks glass and other silicon containing compounds. Reacts with silica to produce silicon tetrafluoride, a hazardous colorless gas.
Hazardous Polymerization:
Will not occur.
Incompatibilities:
Hydrofluoric acid is incompatible with arsenic trioxide, phosphorus pentoxide, ammonia, calcium oxide, sodium hydroxide, sulfuric acid, vinyl acetate, ethylenediamine, acetic anhydride, alkalis, organic materials, most common metals, rubber, leather, water, strong bases, carbonates, sulfides, cyanides, oxides of silicon, especially glass, concrete, silica, fluorine. Will also react with steam or water to produce toxic fumes.
Conditions to Avoid:
Moisture and incompatibles.

11. Toxicological Information


Hydrofluoric acid: Inhalation rat LC50: 1276 ppm/1H; Investigated as a mutagen, reproductive effector.
  --------\Cancer Lists\------------------------------------------------------
                                         ---NTP Carcinogen---
  Ingredient                             Known    Anticipated    IARC Category
  ------------------------------------   -----    -----------    -------------
  Hydrogen Fluoride (7664-39-3)           No          No            None
  Water (7732-18-5)                       No          No            None

12. Ecological Information

Environmental Fate:
If the pH is > 6.5, soil can bind fluorides tightly. High calcium content will immobilize fluorides, which can be damaging to plants when present in acid soils.
Environmental Toxicity:
This material is expected to be slightly toxic to aquatic life. 60 ppm/*/Fish/Lethal/Fresh Water *=time period not specified. > 300ppm/48hr./Shrimp/LC50/Aerated Saltwater

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved incinerator or disposed in a RCRA approved waste facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

14. Transport Information

Domestic (Land, D.O.T.)
-----------------------
Proper Shipping Name: RQ, HYDROFLUORIC ACID (WITH NOT MORE THAN 60% STRENGTH)
Hazard Class: 8, 6.1
UN/NA: UN1790
Packing Group: II
Information reported for product/size: 450LB

International (Water, I.M.O.)
-----------------------------
Proper Shipping Name: HYDROFLUORIC ACID (WITH NOT MORE THAN 60% STRENGTH)
Hazard Class: 8, 6.1
UN/NA: UN1790
Packing Group: II
Information reported for product/size: 450LB


15. Regulatory Information

  --------\Chemical Inventory Status - Part 1\---------------------------------
  Ingredient                                       TSCA  EC   Japan  Australia
  -----------------------------------------------  ----  ---  -----  ---------
  Hydrogen Fluoride (7664-39-3)                     Yes  Yes   Yes      Yes                                      
  Water (7732-18-5)                                 Yes  Yes   Yes      Yes                                      
 
  --------\Chemical Inventory Status - Part 2\---------------------------------
                                                          --Canada--
  Ingredient                                       Korea  DSL   NDSL  Phil.
  -----------------------------------------------  -----  ---   ----  -----
  Hydrogen Fluoride (7664-39-3)                     Yes   Yes   No     Yes          
  Water (7732-18-5)                                 Yes   Yes   No     Yes
 
  --------\Federal, State & International Regulations - Part 1\----------------
                                             -SARA 302-    ------SARA 313------
  Ingredient                                 RQ    TPQ     List  Chemical Catg.
  -----------------------------------------  ---   -----   ----  --------------
  Hydrogen Fluoride (7664-39-3)              100   100     Yes        No
  Water (7732-18-5)                          No    No      No         No
 
  --------\Federal, State & International Regulations - Part 2\----------------
                                                        -RCRA-    -TSCA-
  Ingredient                                 CERCLA     261.33     8(d) 
  -----------------------------------------  ------     ------    ------
  Hydrogen Fluoride (7664-39-3)              100        U134       No        
  Water (7732-18-5)                          No         No         No                                                                
 
 
Chemical Weapons Convention:  No     TSCA 12(b):  No     CDTA:  No
SARA 311/312:  Acute: Yes      Chronic: Yes  Fire: No  Pressure: No
Reactivity: No          (Mixture / Liquid)


Australian Hazchem Code: 2PE
Poison Schedule: S6
WHMIS:
This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.

16. Other Information

NFPA Ratings: Health: 4 Flammability: 0 Reactivity: 1
Label Hazard Warning:
POISON! DANGER! CORROSIVE. EXTREMELY HAZARDOUS LIQUID AND VAPOR. CAUSES SEVERE BURNS WHICH MAY NOT BE IMMEDIATELY PAINFUL OR VISIBLE. MAY BE FATAL IF SWALLOWED OR INHALED. LIQUID AND VAPOR CAN BURN SKIN, EYES AND RESPIRATORY TRACT. CAUSES BONE DAMAGE. REACTION WITH CERTAIN METALS GENERATES FLAMMABLE AND POTENTIALLY EXPLOSIVE HYDROGEN GAS.
Label Precautions:
Do not get in eyes, on skin, or on clothing.
Do not breathe vapor.
Cool before opening.
Use only with adequate ventilation.
Wash thoroughly after handling.
Store in a tightly closed container.
Label First Aid:
IN ALL CASES, CALL PHYSICIAN IMMEDIATELY. First Aid procedures should be pre-planned for HF emergencies. A supply of 50:50 water/magnesium sulfate paste or 2 1/2% Calcium Gluconate paste should be available where first aid medications are administered. If ingested, DO NOT INDUCE VOMITING. If patient is conscious, give large quantities of milk or water and send to hospital. If inhaled and patient is unconscious, give artificial respiration or use inhalator and send to hospital. In case of eye contact, wash open eyes with large but gentle stream of water for 15 minutes. Place ice pack on eyes until reaching emergency room. In case of skin contact, remove contaminated clothing and wash burn area with plenty of water to remove acid. Cover burn area with a poultice of 50:50 water/magnesium sulfate paste or 2 1/2% calcium gluconate paste. Leave in place until medical help arrives or patient is transferred to hospital.
Product Use:
Microelectronics
Revision Information:
MSDS Section(s) changed since last revision of document include: 3.
Disclaimer:
************************************************************************************************
Mallinckrodt Baker, Inc. provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. MALLINCKRODT BAKER, INC. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, MALLINCKRODT BAKER, INC. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION.
************************************************************************************************
Prepared by: Environmental Health & Safety
Phone Number: (314) 654-1600 (U.S.A.)

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