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Remover 1165

 

 


National Variation Control Section Headers Material Safety Data Sheet

 

 

Not APR (6) EU

1. PRODUCT AND COMPANY IDENTIFICATION

 

MICROPOSIT(TM) Remover 1165

 

EUAustraliaEU and Canada USA and CanadaRevision Date Revision date:

11/29/2004

 

Supplier Name & Address

Name of CompanySupplier

 

Name of CompanyRohm and Haas Electronic Materials LLC

Reverse Address Street (Phrase 1)455 Forest Street

TownMarlborough, MA  Postal Code01752  CountryUnited States of America

 

Manufacturer Name & Address �Canada only

 

Telephone

USA & Canada only

For non-emergency information contactFor non-emergency information contact:  National supplierNon emergency phone508-481-7950

 

 

Emergency Telephone Number

Emergency telephone number

National supplier If text & code

Emergency Phone text Chemtrec

Emergency Phone code (number) 800-424-9300

 

Emergency Phone text Rohm and Haas Emergency

Emergency Phone code (number) 215-592-3000

 

Australia & New Zealand onlyEnd AU & NZ only

 

Exclude AU & NZ

2. COMPOSITION/INFORMATION ON INGREDIENTS

SECTION 2.  Composition / information on components

US only

MSDS Composition Component Component

CAS CAS-No.

Concentration Concentration

 

 

1-methyl-2-pyrrolidinone

872-50-4

94.0 -  95.0 %

 

Pyrrolidinone Compound

 

5.0 -  6.0 %

 

Canadian composition

 

 

EU & APR Composition

REG_EU

 

3. HAZARDS IDENTIFICATION

Section 3 Hazards Identification

Emergency Overview

 

Emergency Overview

Form

Appearance

Form

liquid 

Color

Colour

Natural, slightly white 

Odor

Odour

amines   

 

Hazard Summary

Caution!

Combustible liquid and vapor. Causes irritation to eyes, nose, and respiratory tract.

Prolonged, repeated contact with skin may cause drying, defatting, or dermatitis.

 

 

 

 Potential Health Effects

 

Potential Health Effects

Primary Routes of Entry

 Primary Routes of Entry:

Inhalation, ingestion, eye and skin contact.

 

Eyes

Eyes: May cause pain, transient irritation and superficial corneal effects.

 

Skin

Skin: Material may cause irritation.

 

Ingestion

Ingestion: Swallowing may have the following effects:

irritation of mouth, throat and digestive tract

 

Inhalation

Inhalation: Inhalation may have the following effects:

irritation of nose, throat and respiratory tract

 

Target Organs

Target Organs: Eye

Respiratory System

Skin

 

 

Environmental effects

Carcinogenicity �US & Shipley/Rodel

 

Carcinogenicity

Not considered carcinogenic by NTP, IARC, and OSHA

Japan FCIA

 

Taiwan Hazard Class

 

 

4. FIRST AID MEASURES

Section 4 First Aid Measures

Inhalation

Inhalation: Remove from exposure.  If there is difficulty in breathing, give oxygen.  Seek medical attention if symptoms persist. 

 

 

Skin contact

Skin contact: Wash skin with water.  Continue washing for at least 15 minutes.  Obtain medical attention if blistering occurs or redness persists. 

 

 

Eye contact

Eye contact: Immediately flush the eye with plenty of water for at least 15 minutes, holding the eye open.  Obtain medical attention if soreness or redness persists. 

 

 

Ingestion

Ingestion: Wash out mouth with water.  Have victim drink 1-3 glasses of water to dilute stomach contents.  Induce vomiting if person is conscious.  Immediate medical attention is required  Never administer anything by mouth if a victim is losing conciousness, is unconcious or is convulsing. 

Notes to physician

Notes to physician -- treatment

Treat symptomatically. 

5. FIRE-FIGHTING MEASURES

Section 5 Fire Fighting Measures

Flash Point

Flash point

88 �C (190 �F )

 

Auto Ignition Temperature

Lower Explosive Limit

Upper Explosive Limit

 

Minimum ignition energy of dust cloud �indicate cloud vs layer

Thermal Decomposition

Suitable extinguishing media

 

Suitable extinguishing media:

Use water spray, foam, dry chemical or carbon dioxide.

Keep containers and surroundings cool with water spray.

 

Unsuitable extinguishing media

Specific hazards during fire fighting

 

Specific hazards during fire fighting: This product may give rise to hazardous vapors in a fire.  Vapors can travel a considerable distance to a source of ignition and result in flashback. 

Special protective equipment for fire fighters

 

Special protective equipment for fire-fighters: Wear full protective clothing and self-contained breathing apparatus. 

Further information

 

Further information: Pressure may build up in closed containers with possible liberation of combustible vapors.

Other fire safety data

 

 

6. ACCIDENTAL RELEASE MEASURES

Section 6 Accidental Release Measures

Personal precautions

Personal precautions

Wear suitable protective clothing.

Wear respiratory protection.

Eliminate all ignition sources.

 

Environmental precautions

Environmental precautions

Prevent the material from entering drains or water courses.

Do not discharge directly to a water source.

Advise Authorities if spillage has entered watercourse or sewer or has contaminated soil or vegetation.

 

Methods for cleaning up

Methods for cleaning up

Contain spills immediately with inert materials (e.g., sand, earth).

Transfer into suitable containers for recovery or disposal.

Finally flush area with plenty of water.

 

 

Additional advice

Possibly add reference to Sec 15

 

7. Handling and storage

Section 7 Handling and Storage

Handling

Handling

Use local exhaust ventilation.  Avoid contact with eyes, skin and clothing.  Keep container tightly closed. 

Further information on storage conditions

Further information on storage conditions: Keep away from heat, sparks, flame, and other sources of ignition.  Practice good personal hygiene to prevent accidental exposure. 

Advice on protection against fire and explosion

 

Storage

Storage

Storage conditions: Store in original container.  Keep away from heat and sources of ignition.  Storage area should be:  cool  dry  well ventilated  out of direct sunlight 

Other handling and storage

 

 

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Section 8 Exposure Controls/Personal Protection

Exposure guidelines

Exposure limit(s)

 

Exposure limits are listed below, if they exist.

 

 

 

Component

Regulation

Type of listing

Value

 

1-methyl-2-pyrrolidinone

Rohm and Haas

TWA

  10 ppm

 

Rohm and Haas

STEL

  25 ppm

 

Rohm and Haas

Absorbed via skin

 








 

 

 

 

Eye Protection

 

Eye protection: goggles 

Hand Protection

 

Hand protection: Butyl rubber gloves. Other chemical resistant gloves may be recommended by your safety professional. 

Skin & Body Protection

 

Skin and body protection: Normal work wear. 

Respiratory Protection

 

Respiratory protection: Respiratory protection if there is a risk of exposure to high vapor concentrations.  The specific respirator selected must be based on the airborne concentration found in the workplace and must not exceed the working limits of the respirator. 

Hygienic Practices

General Protective Measures

Engineering Controls

 

Engineering measures: Engineering methods to prevent or control exposure are preferred.  Methods include process or personnel enclosure, mechanical ventilation (local exhaust), and control of process conditions. 

 

 

9. PHYSICAL AND CHEMICAL PROPERTIES

Section 9 Physical and Chemical Properties

Appearance

Form

Form

liquid 

Color

Colour

Natural, slightly white 

Odor

Odour

amines   

 

pH

pH

 not applicable

Boiling Point

Boiling point/range

202 �C  (396 �F)

Freezing Point

Flash Point

Flash point

88 �C  (190 �F)

 

Auto Ignition Temperature

Lower Explosive Limit - Dust

Upper Explosive Limit - Dust

Lower Explosive Limit

Upper Explosive Limit

Vapor Pressure

 

Relative Vapor Density

Relative vapour density

Heavier than air.

Solubility in Water

Water solubility

completely soluble

Solubility (quantitative)

Solubility (qualitative)

Partitioning Coefficient

Relative density (Specific Gravity)

Relative density

1.03

Density

Bulk Density

Viscosity (Dynamic)

Flow time

Viscosity (Kinematic)

Evaporation rate

Evaporation rate

Slower than ether

 

Surface Tension

% Volatility

VOC

VOC's

1,030 g/l

General Remarks

Disclaimer

 

NOTE:  The physical data presented above are typical values and should not be construed as a specification.

 

10. STABILITY AND REACTIVITY

Section 10 Stability and Reactivity

Hazardous reactions

Hazardous reactions

Stable under normal conditions.

 

 

Conditions to avoid

Conditions to avoid

 High temperatures  Static discharge 

 

Materials to avoid (InCompatibility)

Materials to avoid

Reducing agents  Oxidizing agents  acids 

 

Hazardous Decomp prods

Hazardous decomposition products

Carbon monoxide, carbon dioxide, nitrogen oxides (NOx),

Polymerization

polymerization

Will not occur.

 

 

11. TOXICOLOGICAL INFORMATION

Toxicological information on this product or its components appear in this section when such data is available.

 

 

Section 11 Toxicological Information

Memo remarks

Acute Oral Tox

Acute Inhalation tox

Acute Dermal tox

Acute tox other route

Skin irritation

Eye irritation

Sensitization

Respiratory system irritation

Chronic/sub-chronic tox

Carcinogenicity

Assessment Carcinogenicity

Toxicity to reproduction

Assessment Toxicity to Reproduction

 

Teratogenecity

Assessment Teratogenicity

Genetic Toxicity in-vitro

Genetic Toxicity in-Vivo

Assessment Mutagenicity

Epidemiology

Further Information

 

_________________________________________________________________________________

Acute Oral Tox

Component: 1-methyl-2-pyrrolidinone

Acute oral toxicity

LD50 guinea pig  1,400 mg/kg

 

Component: 1-methyl-2-pyrrolidinone

Acute oral toxicity

LD50 rat  3,914 mg/kg

 

 

 

 

Component: 1-methyl-2-pyrrolidinone

Acute Dermal tox

Acute dermal toxicity

 

LD50 guinea pig  > 2,000 mg/kg

 

Component: 1-methyl-2-pyrrolidinone

Acute Dermal tox

Acute dermal toxicity

 

LD50 rabbit  8,000 mg/kg

 

 

Acute tox other route

 

Skin irritation

 

Eye irritation

 

Sensitization

 

_________________________________________________________________________________

 

Respiratory system irritation

Chronic/sub-chronic tox

Component: 1-methyl-2-pyrrolidinone

Subchronic toxicity

 

In a 2 year inhalation study, NMP did not cause any life-shortening or carcinogenic effects in rats at 0.04 or 0.4 mg/l (10 and 100 ppm respectively).

 

Carcinogenicity

Assessment Carcinogenicity

Toxicity to reproduction

Assessment Toxicity to Reproduction

Component: 1-methyl-2-pyrrolidinone

Toxicity to reproduction

Several inhalation studies in rats did not reveal any indication of maternal or embryo toxicity. 

 

Teratogenecity

Assessment Teratogenicity

Genetic Toxicity in-vitro

Genetic Toxicity in-Vivo

Assessment Mutagenicity

Component: 1-methyl-2-pyrrolidinone

Mutagenicity

Not mutagenic when tested in bacterial or mammalian systems. 

Epidemiology

Further Information

_________________________________________________________________________________

 

Respiratory system irritation

Chronic/sub-chronic tox

Carcinogenicity

Assessment Carcinogenicity

Toxicity to reproduction

Assessment Toxicity to Reproduction

 

Teratogenecity

Assessment Teratogenicity

Genetic Toxicity in-vitro

Genetic Toxicity in-Vivo

Assessment Mutagenicity

Epidemiology

Further Information

 

12. ECOLOGICAL INFORMATION

Ecotoxicological information on this product or its components appear in this section when such data is available.

 

 

Section 12 Ecological Information

Memo remarks

__________________________________________________________________________________________

 

Additional remarks

 

1-methyl-2-pyrrolidinone

Ecotoxicity Effects

Ecotoxicity effects

Toxicity to fish

Toxicity to fish

 LC50 Bluegill sunfish 96 h 

832 ppm

 

Toxicity to algae

Toxicity to algae

 EC50 Algae 72 h 

>500 ppm

 

Toxicity to bacteria

Toxicity to aquatic inverterbrates

Toxicity to aquatic invertebrates

 EC50 Daphnia magna 48 h 

4897 ppm

 

 

Toxic to soil organisms

 

Chemical Fate Information

Additional remarks

Ecotoxicity Effects

 

Chemical Fate Information

Additional remarks

 

13. DISPOSAL CONSIDERATIONS

Environmental precautions

Environmental precautions: Prevent the material from entering drains or water courses.

Do not discharge directly to a water source.

Advise Authorities if spillage has entered watercourse or sewer or has contaminated soil or vegetation.

 

Section 13 Disposal Considerations

Waste Classification

Disposal

Dispose in accordance with all local, state (provincial), and federal regulations.  Incineration is the recommended method of disposal for containers.  Under RCRA, it is the responsibility of the product's user to determine at the time of disposal, whether the product meets RCRA criteria for hazardous waste.  This is because the product uses, transformations, mixtures, processes, etc. may render the resulting materials hazardous. 

Do not remove label until container is thoroughly cleaned.  Empty containers may contain hazardous residues.  This material and its container must be disposed of in a safe way. 

Contaminated packaging

 EU waste code

 

 

14. TRANSPORT INFORMATION

Japanese FSL and PDSC statements

 

US DOT Information

DOT

 

 

Not regulated for transport 

 

 

IMDG (International Ocean)

IMO/IMDG

 

 

Not regulated (Not dangerous for transport) 

 

CN HAZCHEM

 

Transportation classifications may vary by container volume and may be influenced by regional or country variations in regulations

 

Transport Hazard notes 15. REGULATORY INFORMATION

Section 15 Regulatory Information

Workplace Classification

 

Canadian WHMIS Classification

 

EU Label Phrases

 

SARA 311/312

SARA Title III: Section 311/312 Categorizations (40CFR370): Immediate (acute) Health Hazard

Fire Hazard

 

SARA 302

 

SARA 313

SARA Title III: Section 313 Information (40CFR372)

This product contains a chemical which is listed in Section 313 at or above de minimis concentrations.

SARA Title III Components:

Methyl pyrrolidone

872-50-4

 

 

 

TSCA 12b

US. Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707, Subpt D):

US. Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707, Subpt D)

This product does not contain any substances subject to Section 12(b) export notification.

 

 

CERCLA

HAPS/ODS

Inventories EU

 Inventories ex-EU

 

US. Toxic Substances Control Act (TSCA)  All components of this product are in compliance with the inventory listing requirements of the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory.

 

 

 

National 1

National 2

National 3

Not Japan or Taiwan

Regional (States)

California (Proposition 65)

This product contains a component or components known to the state of California to cause cancer    and/or reproductive harm.

Components:

1-methyl-2-pyrrolidinone

872-50-4

 

 

16. OTHER INFORMATION

 

Hazard Rating

 

Health

Fire

Reactivity

 

NFPA

1

2

0

 

 

 

Legend

Legend

ACGIH

American Conference of Governmental Industrial Hygienists

BAc

Butyl acetate

OSHA

Occupational Safety and Health Administration

PEL

Permissible Exposure Limit

STEL

Short Term Exposure Limit (STEL):

TLV

Threshold Limit Value

TWA

Time Weighted Average (TWA):

|

Bar denotes a revision from prior MSDS.

 

 

 

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

Version: 3.0

 

Print Date:

09/04/2008

Layout 304890

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