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SU-8 Developer

 

 

                                    MATERIAL SAFETY DATA SHEET                               PAGE 1

                                                                                                                               25 February 2005

 

SECTION 1.  CHEMICAL IDENTIFICATION ---------------------------------------------------------

 

CHEMICAL NAME:         Organic Solvent Solution

TRADE NAME:                 SU-8 Developer

PRODUCT #:                      Y020100

 

SECTION 2.  COMPOSITION-----------------------------------------------------------------------------

 

HAZARDOUS

INGREDIENTS:                 1-Methoxy-2-propanol acetate (CAS: 108-65-6), 98-100%

                                             Synonym: propylene glycol monomethyl ether acetate

                                             2-Methoxy-1-propanol acetate (CAS: 70657-70-4), 0-2%

                                            

SECTION 3.  HAZARD DATA----------------------------------------------------------------------------

 

INFLAMMABILITY:        Moderately combustible liquid.

SKIN CONTACT:              No significant signs or symptoms indicative of any health hazard are expected to occur as a result of skin contact. Possible systemic toxicity by skin absorption.

EYE CONTACT:                May cause moderate irritation, including burning sensation, tearing, redness or swelling.

INGESTION:                      Ingestion may cause gastrointestinal discomfort with any or all of the following symptoms: nausea, vomiting, lethargy, or diarrhea.

INHALATION:                  Prolonged overexposure to either vapor or mist may cause coughing, shortness of breath, dizziness and drunkenness.

MUTAGENICITY:            No data available.

CARCINOGENICITY:       Not listed in NTP, IARC, or OSHA as a carcinogen.

TARGET ORGANS:          Eyes, mucous membranes

 

SECTION 4.  FIRST AID MEASURES-------------------------------------------------------------------

                                     

INHALATION:                  If overcome by exposure, remove victim to fresh air immediately. Give oxygen or artificial respiration as needed. Obtain emergency medical attention. Prompt action is essential.

INGESTION:                      If large quantity swallowed, give lukewarm water if victim completely conscious/alert. Do not induce vomiting. Risk of damage to lungs exceeds poisoning risk. Obtain emergency medical attention.

SKIN CONTACT:              Remove contaminated clothing as needed. Wash thoroughly with soap and water. Flush with lukewarm water for 15 minutes. If sticky, use waterless cleaner first. Seek medical attention if discomfort persists.

 

 

EYE CONTACT:                Immediately flush the eyes with large amounts of clean low-pressure water for at least 15 minutes, occasionally lifting the upper and lower lids. If pain or irritation persists, promptly obtain medical attention.

 

SECTION 5.  FIRE FIGHTING MEASURES-----------------------------------------------------------

 

EXTINGUISHING

MEDIA:                                       Water spray, dry chemical, carbon dioxide, or alcohol-resistant foam.

SPECIAL FIRE FIGHTING

PRECAUTIONS:                         Do not enter fire area without proper protection. Wear positive pressure self-contained breathing apparatus (SCBA). Fight fire from a safe distance/protected location.

UNUSUAL FIRE OR

EXPLOSION HAZARDS:          Heat may build enough pressure to rupture closed containers. Use water spray/fog for cooling.

 

SECTION 6.  ACCIDENTAL RELEASE PROCEDURES -------------------------------------------

 

EVACUATION

PROCEDURES & SAFETY:       Wear appropriate protective gear for the situation. See Personal Protection information in Section 8.

CLEANUP & DISPOSAL

OF SPILL:                                    Absorb with an inert absorbent. Sweep up and place in an appropriate closed container (see Section 7). Clean up residual material by washing area with water. Collect washings for disposal.

ENVIRONMENTAL &

REGULATORY REPORTING:  Do not flush to drain. If required proper authorities should be notified.

 

SECTION 7.  STORAGE AND HANDLING PRECAUTIONS---------------------------------------

 

STORAGE:                                  Store in tightly closed, properly vented containers away from heat, sparks, open flame and strong oxidizing agents. Storage under nitrogen is recommended to minimize possible formation of highly reactive peroxides.

HANDLING:                               Keep away from heat, sparks, open flames and strong oxidizing agents.

                                                      Avoid breathing vapors.

                                                      Use with adequate ventilation.

                                                      Avoid contact with skin, eyes, and clothing.  Have available                                        safety shower and eyewash.

                                                      Wear recommended personal protective equipment.

                                                      Wash with soap and water after handling.

 

 

SECTION 8.   EXPOSURE CONTROLS AND PERSONAL PROTECTION-----------------------

 

RESPIRATORY

PROTECTION:                           No occupational exposure limits have been developed for this material. Where exposure through inhalation may occur from use, approved respiratory protection equipment is recommended.

VENTILATION:                          General mechanical ventilation or local exhaust is sufficient under normal conditions.

SKIN PROTECTION:                 Impervious butyl gloves are recommended.

EYE PROTECTION:                   Chemical splash goggles and/or face shields are recommended.

 

SECTION 9.   PHYSICAL AND CHEMICAL DATA--------------------------------------------------

 

APPEARANCE:                          Clear, colorless liquid

ODOR:                                         Aromatic, fruity

BOILING POINT:                       140 �C (284 �F), @ 760mm Hg

SPECIFIC GRAVITY:                 0.96 @ 25 �C (77 �F)

VAPOR PRESSURE:                   3.8 mm Hg @ 25 �C (77 �F)

H2O SOLUBILITY:                     Appreciable (10% or more)

% VOLATILES:                           100% by wt

EVAPORATION RATE:                  0.3 (BuAc = 1)

FLASH POINT:                           47 �C (116 �F) TCC

AUTOIGNITION TEMP:          272 �C (522 �F)

EXPLOSION LIMITS:                1.5% lower (vol%)

                                                      10% upper (vol%)

 

SECTION 10.   REACTIVITY DATA -------------------------------------------------------------------

 

STABILITY:                                                  Stable

INCOMPATIBILITY:                                   Oxidizing Agents, moisture and humidity

HAZARDOUS POLYMERIZATION:        Not expected to occur

HAZARDOUS COMBUSTION OR

DECOMPOSITION PRODUCTS:               Carbon Monoxide and other toxic vapors

 

 

SECTION 11.  TOXICITY HAZARDS-------------------------------------------------------------------

 

PRODUCT SUMMARY:

 

To the best of our knowledge, the toxicological properties have not been thoroughly investigated.

 

ORAL:                          LD50 (rat):               8532 mg/kg

SKIN:                            LD50 (rabbit)           >5000 mg/kg

 

 

 

Repeated dose toxicity �On repeated, prolonged exposure may be a nasal irritant.

 

As 1-Methoxy-2-propanol acetate:

 

ORAL:                          LD50 (rat):               8532 mg/kg

SKIN:                            LD50 (rabbit)           >5000 mg/kg

 

Repeated dose toxicity �No known chronic health effects

 

As 2-Methoxy-1-propanol acetate:

 

Repeated dose toxicity � This material has been shown to cause developmental effects in

offspring of female rabbits exposed to 0, 145, 225, 350 and 545 ppm by inhalation during pregnancy. 145 ppm was the no observed effect (NOEL) in this study.

 

Reproductive/Development effects �Damages developing fetus.

 

SECTION 12.  ECOLOGICAL DATA--------------------------------------------------------------------

 

ECOTOXICITY:                          No data available.

ENVIRONMENTAL FATE:      The material may enter soil and may contaminate water.

BIODEGRADATION:                Data for a closely related material suggest it will be inherently biodegradable.

 

SECTION 13.  DISPOSAL CONSIDERATIONS-------------------------------------------------------

 

Comply with applicable local, state or international regulations regarding the proper disposal of this material and/or containers.

 

SECTION 14.  TRANSPORTATION INFORMATION------------------------------------------------

 

HAZARD CLASSIFICATION:                    Flammable Liquid

SHIPPING NAME:                                       Esters NOS (1-Methoxy-2-propanol acetate)

UN NUMBER:                                              UN 3272

PACKING GROUP                                       III

 

 

SECTION 15.  REGULATORY INFORMATION------------------------------------------------------

 

EUROPEAN INFORMATION

 

EINECS LISTED

EC Nos:  1-Methoxy-2-propanol acetate 203-603-9

 

 

 

RISK & SAFETY PHRASES

R10                 Flammable

R36                 Irritating to eyes

S2                    Keep out of the reach of children

S25                  Avoid contact with eyes

 

INDICATIONS OF DANGER

Xi                    Irritant

 

US AND INTERNATIONAL INFORMATION

 

HAZARDOUS LISTINGS:                           All ingredients appear on the TSCA Inventory of Chemical Substances, EINECS, the Japan Hazardous Chemical Listing and the Canadian DSL.

SARA Title III:                                               This product IS NOT subject to SARA Title III, Section 313 Reporting Requirements.

Calif. SCAQMD Rule 443.1 VOC's:              960 g/l; vapor pressure 3.8 mm Hg @ 25� C

 

 

SECTION 16.   ADDITIONAL PRECAUTIONS AND COMMENTS-------------------------------

 

National Fire Protection Association Hazard Ratings �NFPA:

 

1    Health Hazard Rating
2    Flammability Rating
                  0    Reactivity Rating

 

To the best of our knowledge, the above information is believed to be accurate but does not claim to be all-inclusive and is intended to be used only as a guide.  The supplier makes no warranty of any kind, expressed or implied, concerning the use of this product and shall not be held liable for any damage resulting from handling or from contact with the above product.  User assumes all risks incident to its use.

 

MSDS Revision information:

 

a) Section 14: Updated Transportation information. Changed UN number from UN1993 (Flammable Liquid NOS) to UN3272 (Esters NOS).

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